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Formate Technical Manual, Part B: Compatibilities and Interactions
Section B12: Solubility of Minerals and Salts in Formate Brines

 
 
 
 
 

 
 
 
 
 
 
 
 
 
Interaction between drilling and completion fluids and various minerals is unavoidable when fluids circulate through many thousands of metres of different formation types. When thick sections of salt anhydrate are drilled, it is especially important that the drilling fluid does not dissolve large amounts of formation. Equally, when drilling fluid filtrates and completion brines invade the reservoir and contact the formation brine, it is imperative that insoluble scales are not formed.

The ability of formate well construction fluids to interact with minerals or form scales in the reservoir is determined by the solubility of various minerals and salts in formate brines. This section of the formate manual looks at what is known about the solubility of minerals and salts in formate brines. Formate brines have a unique ability to dissolve alkaline earth metal sulfates, such as barium sulfate, and can serve as scale dissolvers or scale inhibitors for such scales. In addition to extensive solubility data for alkaline earth metal sulfates in formate brines, this section contains solubility data for some salts, such as potassium sulfate, sodium chloride, and magnesium chloride. Solubility data is also included for various clays, silicates, galena, hematite, Ilmenate, and calcium carbonate.
 
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Table of contents: Section B12: Solubility of Minerals and Salts in Formate Brines
Section
Subject
Page number
 B12.1
Introduction
 2
 B12.2 Solubility of alkaline earth metal sulfates in formate brines  2
 B12.2.1 Effect of brine type  2
 B12.2.2 Effect of temperature  3
 B12.2.3 Effect of formate concentration   3 
 B12.2.4 Effect of exposure time  3
 B12.2.5 Effect of pH  3
 B12.2.6 Effect of precipitation reactions  3
 B11.2.7 Practical significance of increased alkaline earth metal sulfate solubility in formate brines  3
 B12.3 Solubility of salts in formate brines  7
 B12.3.1 Solubility of potassium sulfate in potassium formate brine  7
 B12.3.2 Solubility of sodium chloride (NaCl) in potassium formate brine  9
 B12.3.3 Solubility of magnesium chloride (MgCl2) in formate brines  9
 B12.4 Solubility of clays in formate brines  12
 B12.5 Solubility of silicates in formate brines  12
 B12.6 Solubility of galena, hematite, and ilmenate in formate brines  12
 B12.7 Solubility of calcium carbonate in formate brines  12
  References  12
     

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